Wet-spinning of polyester fibers



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United States Patent 2,924,502 WET-SPINNING 0F, gorrnsrnn mans Pompelio A. Ucci, Decatur, Ala., and Arthur H. Stroud, Madison, Wis., assignors to The Chemstrand Corporation, Decatur, Alas, a corporation of Delaware No Drawing. Application December 6', 1956 Serial No. 626,778

10 Claims. (Cl. Ill-54) This invention relates. to the production of filaments and fibers from polyesters and copolyesters and modified polyesters and copolyesters by the wet-spinning method.

More particularly, this invention is concerned with a proc-v ess employing new and novel baths for the coagulation of spinning solutions of such polymers in phenolic solvents.

The simplest form of polymer containing ester linkages is the polyester and it is well known that linear polyesters can be made by heating together a dihydric alcohol or its functional derivativesand a dibasic carboxylic acid or a polyester-forming derivative thereof, such as an acid halide, a salt or a simple ester of a dibasic acid and volatile monohydric alcohol. As heating is continued, particularly in vacuum and/ or in a current of inert gas, condensation continues linearly with formation of longer and longer chains. When these polyesters are in a highly polymerized condition, they canbe formed into filaments, fibers and the like, which can be permanently oriented by cold drawing. That is, when the esterificatio-n reaction is car-- pared by condensation otterephthalic acid or dimethyl terephthalateand a polymethylene glycol containing from two to ten carbon atoms, and particularly etihlyene glycol. These polyesters are relatively insoluble, chemically inactive hydrophobic materials capable of being formed into v filaments which can be hot or cold-drawn to produce i textile filaments and fibers of superior strength and pliability.

Because of the relative insolubility'in most sol vents of these polyesters it has been thought in the past that methods of melt-spinning were the only practical methods to employ in producing filaments and fibers therefrom. In fact, at present the only. methodemployed commercially for converting these polyesters into filaments, fibers, and the like is that of melt-spinning. The wet-spinning method in which a solutionof polyester is extruded into a bath containing a non-solvent for the polyester has a number of advantages over the meltspinning method. For example, the wet-spinning method is generally more economical and can be carried out at lower temperatures. Therefore, plasticizers and other agents may be addedwith a minimum tendency toward discoloration and decomposition. types of plasticizers and modifying agents tend to be less compatible for blending in a melt at high temperatures, whereas they can be readily incorporated in a polyester solution at a low temperature.

There is a scarcity. of suitable solvents for the more" Furthermore, certain Patented Feb. a, 1950 ever, these findings alone have not enabled a commercial-v wet-spinning process for polyesters to be developed.

An important factor in the commercial success of a wetspinning process for producing polyester filaments and fibers is theselection of the coagulating bath. A highly advantageous coagulating bath would be one which could satisfy, among others the following conditions: (A) a bath made with low cost coagulating components; (B) a bath which could be continuously regenerated with facility and high efficiency, particularly as to the recovery and recycling of the solvent component therein for reuse in making the spinning solution; and (C) a bath capable of successful and continuous spinning and of producing suitable fibers under normal type wet-spinning operating conditions.

The coagulating media for polyesters proposed by the prior arthave been water or such a non-solvent as xylene. However, neither of these media has proved successful for filament formation. Water as a precipitant for phenolic solutions of polyesters is far too slow to be of practical use. Water, hot or cold, requires such a long time to extract the phenolic solvents from the extruded stream of polyester solution that support for the extruded stream is required to prevent it from losing shape andforming a pool. The use of xylene as a precipitating or coagulating agent for polyester solutions in phenolic solvents is likewise very impractical. Upon contact with a coagulating bath of xylene an extruded stream of a phenolic solution of polyesters is coagulated and immediately breaks up into minute particles, almost a powder, and showers to the bottom of the coagulating vessel.

The object of this invention is the provision of a Wetspinm'ng method for producing shaped articles, and

specifically filaments and fibers from phenolic solutions ofester polymers or polyesters and modified polyesters and copolyesters. A further object is the provision of a wet spinning process for phenolic solutions of polyesters which employs new and novel coagulating baths in the system. A still further object is provision of such new and novel coagulating baths comprising readily available, economical materials. A still further object is the provision of such coagulating baths which are easily recoverablefor reuse. Another object is the provision of such coagulating bathswhich are capable of successful and continuous spinning thereby producing suitable and saleable filaments and fibers. Other objects of the invention will be apparent from the description thereof hereinafter.

In accordance with the present invention synthetic filamerits, fibers and other shaped articles are formedfrom a polymer or polyester by extruding a solution of the polyester in a phenolic. solvent therefor into a coagulating medium or bath selected from the group consisting of dimethyl sulfoxide and mixtures thereof with Water, and thereafter washing the articles to substantially remove the solvent and coagulating medium.

The synthetic linear condensation polymers contemplated in the practice of the instant invention are those formed from dicarboxylic acids or ester-forming derivation thereof. The esterforming derivatives of dicarboxylic acids most generally commercially employed are the dialkyl esters and the term ester-forming derivatives of dicarboxylic acids is specifically deemed to embrace these ester derivatives. The polyestersand copolyesters useful It has been known that most:

in the instant invention are those produced by reacting or polymerizing one or more glycols of the formula wherein n is an integer from 1 to 4 such as ethylene bis (oxyethanoic) acid, ethylene bis (oxybutanoic) acid, and the like, and the aliphatic and cycloaliphatic aryl esters and half esters, ammonium and amine salts, and acid halides of the above acids. Examples ,of the glycols which may be employed are ethyleneglycol, trimethylene glycol, t'etramethylene glycol, decamethylene glycol, and the like. Polyethylene terephthalate is the preferred polyester because of the ready availability of terephthalic acid and ethylene glycol.

Among the modified polyesters and copolyesters which are useful in the practice of the instant invention are the polyesters and copolyesters defined above modified with monohydroxyl chain terminating compounds, such as monohydric polyalkylene oxides and polyalkylvinylethers having one terminal hydroxyl group. The suitable monohydn'c polyalkylene oxides are those having the general formula wherein R is an alkyl group containing 1 to 4 carbon atoms; m and n are integers from 1 to 22 and x is a whole number indicative of the degree of polymerization, i.e. x may be from 1 to 100, or greater. Examples of such compounds are methoxypolyethylene glycol, ethoxypolyethylene glycol, n-propoxypolyethylene glycol, isop ropoxypolyethylene glycol, methoxypolypropylene glycol, nbutoxypolyoctadecylene glycol, ethoxypolyeicosylene' glycol, and the like. Suitable polyalkylvinyl ethersare the addition polymers prepared by homopolymerization of alkyl vinyl ethers wherein the alkyl group contains from one to four carbon atoms and having one terminal hydroxyl group. Examples of suchcompoundsare polymethylvinyl ether, polypropylvinyl ether, polybutylvinyl.

ether, and the like, having one terminal hydroxyl group. These modified polyesters and copolyesters can be prepared by the methods set out in the copending application of W. A. H. Huffman, Serial No. 55 3,433, filed December 16, 1955, now U.S. Patent No. 2,905,657,

Other modified polyesters and copolyesters useful in the practice of the instant invention are those modified with cross-linking agents together with a chain terminating agent as set out above. Thus, they include polyesters and copolyesters modified with chain terminating compounds having the general formula (I) and polyalkylvinyl ethers having'oneterminal hydroxyl group wherein the alkyl groups contain from 1 to 4 carbon atoms, together with cross-linking agents which are polyfunctional acids and alcohols with a funtionality greater than two, or their simple derivatives. Theacids and their derivatives are compounds having the general formula in which R is an alkyl group having 1 to 3 carbon atoms, R is hydrogen, methyl, or ethyl, and n is an integer from 3 to 5 inclusive. Among such compounds are trimethyl trimesate, tetramethyl mellophonate, trimethyl trimellitate, tetramethyl prehnitate, tripropyl trimesate and ring alkylated esters of benzene tricarboxylic acids. Polyfunctional alcohols or their simple derivatives which may be used as cross-linking agents are the saturated aliphatic or cycloaliphatic polyhydric alcohols containing only C, H, and 0, having the general formula (III) )n wherein R is a saturated aliphatic or a cycloaliphatic group having from 3 to 6 carbon atoms and n is an integer greater than 2. Examples of such compounds are pentaerythritol, sorbitol, glycerol, mannitol, and the like. These modified polyesters and copolyesters can be prepared by the methods set out in the copending application of W. A. H. Huffman, Serial No. 553,424, filed December 16, 1951, now U.S. Patent No. 2,895,946.

Additional modified polyesters and copolyesters useful in the practice of the present invention are those polyesters and copolyesters defined above modified with long chain aliphatic dicarboxylic acids or the dialkyl esters thereof in which the aliphatic chain contains from 15 to 25 carbon atoms. Such acids and their dialkyl esters have the general formula 22, n can be only zero in order that the aliphatic chain contain no more than 25 carbon atoms. The R substituent can be located atany point between the carboxyl groups. The alkyl side chain represented by R is preferably methyl or ethyl. The dialkyl esters are preferably those in which *the alkyl group represented by R contains from 1 to 5 carbon atoms. Examples of suitable long chain aliphatic acids include pentadecanedioic acid, octadecanedioic acid,

nonadecanedioic acid, eicosanedioic acid, heneicosanedioicacid, docosanedioic acid, S-ethyl octadecanedioic acid, 9- methyl nonadecanedioic acid, 9-methyl eicosan'edioic acid, and mixtures thereof. Examples of suitable dialkyl esters of the long chain aliphatic acids include dimethyl pentadecanedioate, diethyl octadecanedioate, dimethyl nona-v decanedioate, dimethyl .eicosanedioate, diethyl eicosane- ,dioate, dipropyl eicosanedioate, dimethyl heneicosanedioate, dimethyl 9-ethyloctadeoanedioate, diethyl 9-methyl nonadecanedioate, dimethyl 9-methyleicosanedioate, and the like, and mixtures thereof.

These polyesters and copolyesters modified with long chain aliphatic dicarboxylic acids and dialkyl esters there of can be prepared in the same manner as the polymethylene-dicarboxylic acid polyesteis previously known, employing the same conditions and catalysts, in a two stage reaction. Thus, the long chain aliphatic dicarboxylic acids are added to the original charge of a polymethylene glycol and a suitable dicarboxylic acid and reacted in the presence of a catalyst at elevated temeperatures, usually from about to 220 C., and atmospheric pressure to form water and the bis-Z-hydroxyalkyl dicarboxylate monomer. Alternatively, the dialkyl esters of the long chain aliphatic dicarboxylic acids are added to the charge of a polymethylene glycol and a dialkyl ester of a suitable dicarboxylic acid and the'mixture caused to undergo an ester interchange reaction to produce'one or more volatile alcohols and the bis-Z-hydroxyalkyl dicarboxylate monomer. Thereafter, in the second stage, the monomer is e e ns l hi e empera e n r l y o bo 260 C., under reduced pressure-and in the presence of the same or a different catalyst to form the modified polyester with elimination of a monomeric polymethylene glycol which is readily volatilized. The second, or poly-, merization, stage is continued until a polyester having the desired degree of polymerization is obtained. This stage generally requires from-about 1 to 6 hours to obtain a sufiiciently high degree of polymerization to yield filamentforming polymers.

The solvents useful in the present invention are strongly polar solvents derived from phenols and may be referred to generally as phenolic solvents. The preferable phenolic solvents used herein are phenol, mixtures of phenol with from 1 to 15 percent water, and meta-cresol. Other phenolic solvents which are also suitable for use in'the process include mixtures of phenol with from to percent resorcinol, mixtures of phenol with from 5 to 50* percent chloral hydrate, mixtures of phenol with 5 to 15 percent chloral amide, mixtures of phenol with from 5 to 99 percent 2,4,6-trichlorophenol, 6 -tertbutyl-meta-cresol, resorcinol monomethyl ether, and 2,4,6rtrichlorophenol. The maximum solids concentrations of the polyesters that can be obtained in solution and the viscosity of the solutions depend upon the nature of the polyester, the solvent or solvent. mixture and the temperature. Solutions having polymer concentrations of from about percent to as high as 40. percent can t be successfully coagulated into. good strength fibers by means of the present invention. It is preferred to employ solutions containing from about to about percent polymer.

The coagulating or setting baths employed in the present invention can contain water in any amount from a trace up to 50 percent by volume. Since water has been found to slow the coagulation of polyester solutions in dimethyl sulfoxide, it is generally preferred to use only up to about 35 percent of water by volume in the baths. The coagulating or setting baths can be used at any convenient temperature ranging from just above the freezing point to the boiling point; of the constituents of the bath. Preferably,-the baths are employed from about 20 C. up to the boiling point. A minimium of experimentation will establish a range of optimum temperatures for any particular polyester, solvent, and spinning solution concentration selected. The temperature can be adjusted to effect a reasonable speed in the coagulation of the articles. Thus, if coagulation is a little too slow at one temperature, it is possibleto warm the baths, which speeds up the process, of precipitation and setting. i

The process of this invention may be carried out by extruding the polyester solutions in the normal manner of webspinning processes, ie by means of a spinneret having one or more. apertures in the face thereof. which has been immersed in the coagulating or setting bath.

This is the preferred method of carrying out the process of this invention. Alternatively the spinning method known as dry jet-wet spinning may be employed wherein the spinneret is positioned a' short distance above the surface of the coagulating or setting bath. The coagulating bath itself may be. of any desired length necessary to fully coagulate and precipitate the polyester solution, and may have positioned therein suitable filament guides, rollers, or other supporting members as required. The filament or filaments, as the case may be, are moved from the coagulating bath and passed through a washing medium where all the residual solvent and coagulating liquid are removed therefrom. Water is the preferred washing medium and is usually contained in a bath through which the filaments are passed. Washing rolls or like apparatus, such. as godets, threadadvancing reels, or bobbins may also. be employed. Thereafter the filaments are dried, if" desired, prior to be cut into short, discontinuous lengths to form staple fibers by any convenient means. The present invention also contemplates the imposition of sufficient tension upon the filament or other article in the coagulating or setting baths to elongate the filament or other article while coagulation is taking place. For this purpose, the conventional winding or take up devices may have their peripheral speed adjusted to any speed which will impose a tension upon the filament. Since shrinkage in the coagulating bath occurs if the filament is relaxed, speeds of less than, equal to, and greater than the rate of extrusion of the polymer solutions will result in such tension.

The following examples will serve to further illustrate the process of the present invention. The invention is not, however, limited to the specific embodiments shown in the examples, but is limited only by the scope of the appended claims.

Example I A spinning solution was prepared containing 30 percent by weight of a modified polyethylene terephthalate polymer in a solvent consisting of 90 parts of phenol and 10 parts of water by weight. The polymer was prepared from ethylene glycol, dimethyl terephthalate, and a mixture composed of approximately 57 percent of the dimethylester of eicosane-l,20dioic acid and approximately 43 percent of the dimethyl ester of S-ethyloctadecane-l,18-dioic acid and in which 30 percent of the total diesters charged were the long chain aliphatic diesters. A slurry of the ground polymer mixed with the phenol-water solvent was heated to approximately 90 C., until solution was complete, filtered through a sintered glass funnel and cooled to approximately 30 C. with no gelling. The clear, pourable solution was divided into four parts and extruded through a spinneret into four coagulating or spin baths at room temperature. The baths had the following compositions: (1) 95 percent dimethyl sulfoxide and 5 percent water by volume, (2) 90 percent dimethyl sulfoxide and 10 percent water. by volume, (3) percent dimethyl sulfoxide and 15 percent water by volume, and (4) 80 percent dimethyl sulfoxide and 20 percent water by volume. Mono-filaments were rapidly set up and were conveyed by a system of guides to take-up rolls through a water bath at a temperature of C. All four of the baths enabled putting the filaments under positive tension in the coagulating bath as well as in the water bath to produce well-oriented, drawn filaments. After washing the filaments could be further cold-drawn to increase their tensile strengths.

Example II A spinning solution containing 30 percent of the same modified polyethylene terephthalate polymer described in Example 1 above was prepared by the same procedure in the same 90 percent phenol, 10 percent water solvent. After solution was complete the spinning solution was filtered and cooled to room temperature, approximately 30 C. The resulting clear, pourable spinning solution was extruded from a spinneret having 10 holes of 0.0035

diameter into a coagulating or spin bath of 75 percent dimethyl sulfoxide and 25 percent water by volume at room temperature. The filaments were set up to good strength. They were subjected to a 0.5 stretch ratio, i.e., ratio in speed of take-up roll to extrusion speed, in the coagulating bath and a further stretch ratio of 4.0 times in the boiling water wash bath which followed the coagulating bath. The filaments displayed excellent strength, and could be further oriented by cold-. drawing after washing.

Example III A spinning solution containing 30 percent of the same modified polyethylene terephthalate polymer described in Example I above was prepared by the same procedure in a solvent consisting of 90 percent phenol and 10 percent water by weight. After solution was complete the spinningsolution was filtered and cooled to room temperature. The resulting clear, pourable spinning solution was extruded from a spinneret having 40 holes of 0.0030 inch diameter into a coagulating or spin bath consisting of 70 percent dimethyl sulfoxide and 30 percent water by weight at 50 C. The filaments were rapidly set up. The filaments were subjected to a stretch ratio of 0.96 times in the spin bath, 6.40 times in the boiling water wash bath which followed, and 0.91 times while drying in air. ,The filaments so produced had a denier of 2.65 per filament, a tenacity of 1.62 grams per denier, and an elongation of 30 percent.

Example IV The same spinning solution as prepared in Example Ill above was prepared by the same procedure, filtered, and cooled. The clear spinning solution was then extruded into a coagulating or spin bath consisting of dimethyl sulfoxide at 33 C. through a spinneret having 40 holes of 0.0030 inch diameter. The filaments were subjected to a positive tension in the spin bath and in the water bath at 89 C. which followed the spin bath. The filaments produced possessed good strength and could be further oriented by cold-drawing.

Example V A spinning solution containing 25 percent of a polyethylene terephthalate polymer modified with 0.25 percent pentaerythritol and 18 percent methoxypolyethylene glycol having a molecular weight of 2,000 was prepared by mixing 15 grams of the polymer in the form of lathe turnings with 45 grams of a solvent consisting of 90 parts of phenol, parts of water. The mixture was heated to approximately 130 C. in an oil bath with stirring until solution was complete. The spinning solution was then filtered through a sintered glass funnel,

of the ground polymer in a solvent consisting of 90 parts of phenol and 10- parts of water by weight at a temperature of approximatelylQOl C. in the samemanner as described above. The resultingsolution was filtered and maintained at approximately 60 C. in a jacketed vessel. The clear, pourable solution was flowed onto a glass plate and coagulated by immersing the plate and solution in a bath of dimethyl sulfoxide at room temperature. Coagulation was immediate, and when separated from the plate the coagulated polymer had formed a tough, colddrawable film suitable for packaging and laminating purposes.

cooled to approximately 60 C. and placed in a reservoir consisting of a two-inch jacketed stainless steel pipe maintained at 60 C. Nitrogen gas pressure of about 16 pounds per square inch was applied to the spinning solution and a filament was extruded through a spinneret into a coagulating or spin bath consisting of 70 percent dimethyl sulfoxide and 30 percent water by weight at 50 C. The filament could be subjected to a positive tension in the spin bath and in the boiling water wash bath which followed it. The filament so produced possessed good strength and could be further oriented by subsequent colddrawing.

Example VI A 30 percent solution was prepared from a polyethylene terephthalate polymer modified by the inclusion of 10 percent by weight of methoxypolyethylene glycol having a molecular weight of 2,000 by mixing. 15 grams of the polymer in the form of lathe turnings with grams of a solvent consisting of 90 parts of phenol, 10 parts of water. The mixture was heated to approximately 130 C. in an oil bath with stirring until solution was complete. The spinning solution was then filtered through a sintered glass funnel, cooled to approximately 60 C. and placed in the solution supply tube of an apparatus similar to that described in Example V above having a water jacket maintained at 60- C. Nitrogen gas pressure was applied to the spinning solution and a filament was extruded from a spin'ner'et into a coagulating or spin bath consisting of 70' percent dimethyl sulfoxide and 30 percent water by weight at C. The filament was rapidly set up and could be subjected to positive tension both in the spin bath and the boiling water wash bath which followed it. The filament produced had good strength and could be further oriented by cold-drawing.

Example VII A-solution containing 20 percent by weight of polyethylene terephthalate'was prepared by heating a slurry The process of the present invention makes possible the formation of a variety of shaped articles from polyesters by means of wet-spinning methods. In contrast to previous attempts'to wet-spin these polymers, it is possible to withdraw from the coagulating baths filaments and other shaped articles of good immediate strength, and to subject the articles to positive tensions in the coagulating bath as well as the wash baths. These articles, and particularly filaments, possess superior tensile properties when washed and stretched, which can then be further improved by cold or hot-drawing. Although the process of this invention has been illustrated as applicable to the formation of filaments, fibers, and films, the invention is not restricted thereto, since it is also useful for the formation of a variety of objects, such as surgical sutures, fishing leaders, fishing lines, dental floss, ribbons, tubes, sheets, bands, and the like.

The properties of the shaped articles formed by the process of this invention maybe modified by appropriate modification of the spinning solutions. Thus, the spinning solutions may have incorporated therein various modifying agents, such as plasticizers, dyes, pigments, diluents, resins, cellulose derivatives, waxes, water repellents, luster modifying agents, flame repellents, and the like. The properties of the shaped articles may also be modified by the'application thereto of any desired textile finish composition, such as antistatic agents, lubricants, sizes, and the like. Moreover, the process of the present invention can be utilized to produce a finished textile yarn by employing continuous dyeing means after the removal of the residual solvent and coagulating liquid by washing. If desired, a finish can thereafter be applied to the filaments or yarn.

As many apparently widely diiferent embodiments of this invention may be made without departing from'the spirit and scope thereof, it is to be understood that the invention is not limited to the specific embodiments thereof except as defined in the appended claims.

We claim:

1. A process for forming shaped articles from a polyester polymer which comprises extruding a solution of a synthetic linear condensation polyester in a solvent therefor comprising a phenol in major proportion into a coagulating medium selected from the group consisting of dimethyl sulfoxide and mixtures thereof with up to 50 percent water by volume, and thereafter washing the shaped articles with water, said polyester comprising the reaction product of at least one dicarboxylic acid andat least one'glycol of the series HO(CH ),,OH wherein n is an integer from 2 to 10.

2. The process as defined in claim 1' wherein the said polyester is modified by a chain-terminator which is methoxypolyethylene glycol. I

'3. The process asdefined in claim 1 wherein the said polyester is modified by a chain-terminator which is methoxypolyethylene glycol and a cross-linking agent which is trimethyl 'trimesate.

4. The processas defined in claim 1 wherein the said polyester ismodified by a chain-terminator which is methoxypolyethylene glycol and a cross-linking agent which is" pentaerythritol;

' 5. 'Thep'rocess as defined in claim 1 wherein the said polyester contains in polymerized form a mixture of the 9 dimethyl ester of eicosane-1,20-dioic acid and the dimethyl ester of 8-ethyl octadecane-l,18-dioic acid.

6. The process as defined in claim 1 wherein the polyester is polyethylene terephthalate.

7. The process as defined in claim 1 wherein the solvent is a mixture of phenol and from 1 to 15 percent water.

8. The process as defined in calim 1 wherein the coagulating medium is dimethyl sulfoxide.

9. The process as defined in claim 1 wherein the coagulating medium is a mixture of dimethyl sulfoxide and up to 50 percent water by volume.

10. A process for forming shaped articles from a polyester polymer which comprises extruding a solution containing from 20 to 40 percent by weight of a synthetic linear condensation polyester in a solvent therefor comprising a phenol in major proportion into a coagulating medium selected from the group consisting of dimet-hyl sulfoxide and mixtures thereof with up to 50 percent water by volume, maintained at a temperature of from about 20 C. up to the boiling point of the coagulating medium, and thereafter washing the shaped articles with water, said polyester comprising the reaction product of at least one dicarboxylic acid and at least one glycol of the series HO(CH ),,--OH wherein n is an integer from 2 to10.

References Cited in the file of this patent UNITED STATES PATENTS 2,404,717 Houtz July 23, 1946 2,556,295 Pace June 12, 1951 2,597,643 Izard May 20, 1952 

1. A PROCESS FOR FORMING SHAPED ARTICLES FROM A POLYESTER POLYMER WHICH COMRPISES EXTRUDING A SOLUTION OF A SYNTHETIC LINEAR CONDENSATION POLYESTER IN A SOLVENT THEREFOR COMPRISING A PHENOL IN MAJOR PROPORTION INTO A COAGULATING MEDIUM SELECTED FROM THE GROUP CONSISTING OF DIMETHYL SULFOXIDE AND MIXTURES THEREOF WITH UP TO 50 PERCENT WATER BY VOLUME, AND THEREAFTER WASHING THE SHAPED ARTICLES WITH WATER, SAID POLYESTER COMPRISING THE REACTION PRODUCT OF AT LEAST ONE DICARBOXYLIC ACID WHEREIN N IS AN INTEGER FROM 2 TO
 10. 